Process and burner for hydrocarbon partial oxidation

ABSTRACT

A hydrocarbon partial oxidation process for obtaining gaseous mixtures comprising hydrogen and carbon monoxide is carried out through a burner ( 10 ) comprising a mixing chamber ( 12 ) that has an inner side wall ( 12   a ) extending between at least one inlet opening ( 23, 23   a ) and an outlet opening ( 24 ), independent gaseous flows of hydrocarbons and oxygen, respectively, being continuously fed into said mixing chamber ( 12 ) to form a gaseous mixture advancing towards said outlet opening ( 24 ) to be fed into a combustion chamber ( 14 ) of the gaseous mixture itself; into said mixing chamber ( 12 ) and substantially in contact with the inner side wall ( 12   a ) thereof, a flow of an inert fluid is also fed in equicurrent to said gaseous mixture, with formation of a respective annular flow of inert fluid, enveloping said gaseous mixture from which it is substantially separated by a respective inner limit layer, said annular flow of inert fluid having, at said limit layer, an advancing speed at least equal to the speed of propagation of the flame in said gaseous mixture.

FIELD OF APPLICATION

The present invention refers to a hydrocarbon partial oxidation processfor obtaining gaseous mixtures comprising hydrogen and carbon monoxidelike, for example, synthesis gas, combustible gas or reduction gas.

In particular, the present invention refers to a hydrocarbon partialoxidation process through a burner comprising a mixing chamber that hasan inner side wall extending between at least one inlet opening and anoutlet opening, independent gaseous flows of hydrocarbons and oxygen,respectively, being continuously fed into said mixing chamber to form agaseous mixture advancing towards said outlet opening to be fed into acombustion chamber of the gaseous mixture itself.

In the rest of the description and in the subsequent claims, with theterm “hydrocarbons” we mean to generically indicate a hydrocarbon ormixtures of hydrocarbons that can be saturated and/or unsaturated, lightand/or heavy (for example C1-C6); with the term “gaseous flow ofhydrocarbons”, on the other hand, we mean to indicate a fluid comprisinggaseous hydrocarbons, such as the methane or the natural gas, or else agaseous flow comprising solid fuels in suspension (for example coalslack or carbon-black) or furthermore a gaseous flow comprising liquidhydrocarbons in dispersion (for example light or heavy hydrocarbons suchas the naphtha and the fuel oil).

PRIOR ART

As known, to obtain synthesis gases or other similar gaseous mixturescomprising hydrogen and carbon monoxide (which are used for example inthe production of ammonia and methanol) through hydrocarbon partialoxidation carried out with suitably structured burners, there is an everincreasing requirement to realize a high-yield process, which is easy tocarry out and does not require high energy consumption and operatingcosts.

In order to satisfy the aforementioned requirement, processes aregenerally used according to which the gaseous flows comprising oxygenand hydrocarbons, respectively, are fed and made to react for thedesired partial oxidation of the hydrocarbons, in a combustion chamber,also known as gassifier, where a flame forms. Structurally, the burneris at least partially inserted into the gassifier.

In accordance with the prior art, the axial speed of feeding of the twogaseous flows into the burner must be sufficiently high to prevent theflame from returning towards the burner.

Although advantageous from various points of view, the partial oxidationprocesses of hydrocarbons according to this prior art, i.e. that ofso-called diffusion burners, have recognized drawbacks, including, inparticular, a production of carbon-black due to a substantialpyrolization of those hydrocarbons that, in the combustion chamber, comeinto contact and mix with the hot gases produced by the combustion,before being able to be suitably mixed with oxygen.

Moreover, the production of carbon-black in the combustion chamber has anegative influence both on the global yield of the oxidation processintended to be realized, with particular reference to the smaller amountof hydrogen and carbon monoxide that can be obtained per unit of burnthydrocarbon, and on the operation of the plants downstream of thegassifier. Indeed, it is necessary to separate the carbon-black from thereaction products to prevent, for example, it from dirtying apparatusesdownstream of the gassifier, such as a possible boiler or a possiblecatalyst (with the result of poisoning it).

Resulting from this, for such a separation, there is a need for a wholeseries of operating steps that involve relative energetic consumption,high complexity of the plant and high maintenance costs.

In order to overcome the aforementioned drawbacks, partial oxidationprocesses of hydrocarbons have been adopted that allow the production ofcarbon-black to be reduced, but they have the major disadvantage ofhaving to operate in the combustion chamber with very high temperatures(in the order of 1300-1400° C.), therefore with high oxygen consumption,a consequent low conversion yield and high operating costs.

In the prior art processes have also been researched in which thegaseous flows comprising oxygen and hydrocarbons, respectively, arepreliminarily intimately mixed in a mixing chamber provided in theburner itself, before their entry into the combustion chamber, so as toavoid the formation of carbon-black.

However, this type of solution (burners with premixing) has never beenrealized with hydrocarbon gaseous flows because this involves arecognized and very serious drawback, i.e. the high risk of the flamereturning towards the mixing chamber itself of the burner.

SUMMARY OF THE INVENTION

The problem underlying the present invention is that of providing aprocess for hydrocarbon partial oxidation, capable of satisfying therequirement outlined above, at the same time overcoming the quoteddrawbacks with reference to the prior art in a simple and cost-effectiveway.

This problem is solved, according to the present invention, by ahydrocarbon partial oxidation process through a burner comprising amixing chamber that has an inner side wall extending between at leastone inlet opening and an outlet opening, independent gaseous flows ofhydrocarbons and oxygen, respectively, being continuously fed into saidmixing chamber to form a gaseous mixture advancing towards said outletopening to be fed into a combustion chamber of the gaseous mixtureitself, characterized in that, into said mixing chamber andsubstantially in contact with the inner side wall thereof, a flow of aninert fluid is also fed in equicurrent to said gaseous mixture, withformation of a respective annular flow of inert fluid, enveloping saidgaseous mixture from which it is substantially separated by a respectiveinner limit layer, said annular flow of inert fluid having, at saidlimit layer, an advancing speed at least equal to the speed ofpropagation of the flame in said gaseous mixture.

Further characteristics and the advantages of the process forhydrocarbon partial oxidation according to the present invention shallbecome clearer from the description, made hereafter, of a preferredembodiment thereof, given for indicating and not limiting purposes, withreference to the attached drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 schematically represents a longitudinal section of a burner forhydrocarbon partial oxidation according to the present invention.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

With reference to the FIGURE, a burner for hydrocarbon partialoxidation, for obtaining gaseous mixtures comprising hydrogen and carbonmonoxide, in accordance with the present invention is shown and it isglobally indicated with 10.

Said burner 10 is at least partially inserted into a combustion chamber14 of a gassifier, per se conventional and therefore not represented indetail, and comprises a mixing chamber 12 that is in fluid communicationwith the combustion chamber 14.

The mixing chamber 12 has an inner side wall 12 a extending between aninlet opening 23 and an outlet opening 24. Independent gaseous flows ofhydrocarbons and oxygen, respectively, are continuously fed into saidmixing chamber 12 to form a gaseous mixture advancing towards saidoutlet opening 24 to be fed into said combustion chamber 14 of thegaseous mixture itself. More specifically, the independent gaseous flowsare fed into the mixing chamber 12 from an inlet opening 23 and from afurther inlet opening 23 a, arranged in an intermediate position betweensaid inlet opening 23 and said outlet opening 24, preferably close tothe inlet opening 23 as is shown in the example of the FIGURE.Alternatively, the further inlet opening 23 a can be arranged, in theburner 10, at the same height as the inlet opening 23.

Preferably, the inlet opening 23 feeds the flow of oxygen whereas theinlet opening 23 a feeds the flow of hydrocarbon.

Going into greater detail, the combustion chamber 14 is defined by awall 15 that is equipped with a circular opening 16 in which acylindrical body 18 of the burner 10 is partially inserted. Thecylindrical body 18 is fixed to the circular opening 16 of the wall 15through a flange 20, arranged outside the cylindrical body 18.

The cylindrical body 18 at one end 22 defines said mixing chamber 12that is cylindrical-shaped, with cylindrical side wall 12 a, said end 22being the end of the cylindrical body 18 inserted into the combustionchamber 14. The end 22 has said outlet opening 24 that puts said mixingchamber 12 in communication with said combustion chamber 14.

A duct 26 carrying oxygen and a duct 28 carrying hydrocarbons areconnected to the two inlet openings 23 and 23 a of the mixing chamber12, respectively. More specifically, the two ducts 26 and 28 aresubstantially two cylindrical pipes, inner 30 and outer 32, coaxial andconcentric, contained in the cylindrical body 18: the inner pipe 30feeds oxygen and the annular interspace between the two inner 30 andouter 32 pipes feeds hydrocarbons.

In particular, in accordance with an advantageous aspect of the presentinvention, such a mixing chamber 12 is also fed by a duct 34 carryinginert fluid. More precisely, the duct 34 is arranged in such a way thatthe inert fluid licks said side wall 12 a of the mixing chamber 12.

In the present application, by inert fluid we mean a fluid that preventsthe generation and propagation of the flame, in the combustion operativeconditions present in the gassifier. Preferably a gas like steam isused. Other gases, like for example pure gases (for example nitrogen ormethane or oxygen), or mixtures of gases that have the aforementionedcharacteristic can be used.

Preferably, the flow of inert fluid is fed close to the outlet opening24 of the mixing chamber 12.

Preferably, the duct 34 carrying inert fluid is substantially acylindrical pipe 36, arranged coaxially and concentrically with theouter pipe 32 and contained in the cylindrical body 18: the annularinterspace between the cylindrical pipe 36 and the outer pipe 32 feedsthe inert fluid.

Advantageously, the cylindrical pipe 36 constitutes the inner side wallof the cylindrical body 18, an end portion of the side wall 12 a of themixing chamber 12 being formed by a portion of cylindrical pipe 36 thatis situated close to the opening 24 of the cylindrical body 18: saidportion of cylindrical pipe 36 defines a cylindrical portion 38 of themixing chamber 12.

The outer pipe 32, which, as stated, is coaxial to the cylindrical pipe36, is shorter than the cylindrical pipe 36.

Moreover, the inner pipe 30, which, as stated, is coaxial to the outerpipe 32, is shorter than the outer pipe 32.

Since, as stated, the inner pipe 30 feeds the oxygen and the interspacebetween the two inner 30 and outer 32 pipes feeds the hydrocarbons, afurther cylindrical portion 38 a of mixing chamber 12 is formed betweenthe end of the inner pipe 30 and the end of the outer pipe 32, definedby a portion of outer pipe 32.

Preferably, in the end portion of the inner pipe 30, in the end portionof the interspace between inner pipe 30 and outer pipe 32 and in the endportion of the interspace between outer pipe 32 and cylindrical pipe 36,per se known swirlers 40, 42 and 44 are respectively provided. Inpractice, the end of the swirler 40 constitutes the inlet opening 23 andthe end of the swirler 42 constitutes the further inlet opening 23 a.

It should also be specified that, in the wall of the pipe 36 thatdefines the portion of cylindrical body 18 inserted in the combustionchamber 14, a cylindrical recess 46 is advantageously provided, in fluidcommunication with an inlet fitting 48 and an outlet fitting 50 of acooling fluid.

The inlet 48 and outlet fitting 50 are arranged outside of thecombustion chamber 14 and in the cylindrical recess 46 a cylindricalbaffle 52 is provided that defines two coaxial and concentric inner andouter cylindrical chambers 54 and 56, in fluid communication with eachother and, respectively, with the inlet fitting 48 and with the outletfitting 50. Advantageously, the cylindrical chamber 54 defines a portionof the inner side wall of the cylindrical body 18, and in particulardefines the duct 34 carrying inert fluid and the end portion of the sidewall 12 a of the mixing chamber 12.

It should also be specified that the opening 24 is circular and that itis formed by the end 22 of the cylindrical body 18, which is preferablytapered towards the centre.

The operation of the burner for hydrocarbon partial oxidation accordingto the invention is specified hereafter.

In short, a hydrocarbon partial oxidation process according to theinvention, through a burner 10 comprising a mixing chamber 12 that hasan inner side wall 12 a extending between at least one inlet opening 23and an outlet opening 24, comprises the continuous feeding into saidmixing chamber 12 of independent gaseous flows of hydrocarbons andoxygen, respectively, to form a gaseous mixture advancing towards saidoutlet opening 24 to be fed into a combustion chamber 14 of the gaseousmixture itself.

According to an aspect of the present invention, the process alsocomprises a step of feeding, into said mixing chamber 12 andsubstantially in contact with the inner side wall 12 a thereof, of aflow of an inert fluid in equicurrent to said gaseous mixture, withformation of a respective annular flow of inert.

This annular flow envelops said gaseous mixture and it is substantiallyseparated from it by a respective inner limit layer. The annular flow ofinert has, at said limit layer, an advancing speed at least equal to thespeed of propagation of the flame in said gaseous mixture.

In other words, the gaseous mixture that advances in the mixing chamber12 towards the combustion chamber 14 has a substantially parabolic speedprofile, with maximum advancing speed substantially at the centre of themixing chamber 12 and substantially zero speed at the inner side wall 12a of said mixing chamber 12.

In the combustion chamber 14 the gaseous mixture is made to react,obtaining a flame and a gaseous flow comprising hydrogen and carbonmonoxide, said flame having a predetermined speed of propagation in asaturated environment of said gaseous mixture.

In practice, the flow of inert fluid licks said side wall 12 a of themixing chamber 12 up to a determined distance from said side wall 12 a,i.e. up to a distance that corresponds to the aforementioned inner limitlayer.

The flow of inert fluid has substantially zero speed at the side wall 12a of said mixing chamber 12 and increasing speed in a substantiallyparabolic manner as one moves away from the side wall 12 a up to amaximum speed of said inert fluid at said determined distance from theside wall 12 a, i.e. at the distance of the inner limit layer.

The gaseous mixture thus takes on a substantially parabolic speedprofile, with maximum advancing speed substantially at the centre of themixing chamber 12 and minimum speed substantially equal to said maximumspeed of the inert fluid at said predetermined distance from the sidewall 12 a: said maximum speed of the inert fluid, according to theinvention, is greater than said speed of propagation of the flame.

More specifically, the flow of oxygen, which is fed from the inner pipe30, mixes in the further portion 38 a of mixing chamber 12 with the flowof hydrocarbons.

The mixing speed is increased by feeding the flow of hydrocarbons andthe flow of oxygen at substantially the same axial speed. The flows ofhydrocarbons and oxygen respectively cross the swirlers 40 and 42, whichgive each of the two flows helical motion, in opposite directions withrespect to each other.

Preferably, the opposite helical motions have momentum of momentum ofsubstantially the same value: in this way, the mixed flow shalladvantageously just have the axial speed component.

Alternatively, it is possible to provide just one of the swirlers 40 and42, consequently giving helical motion to just one flow.

Leaving the further portion 38 a of mixing chamber 12, the gaseousmixture thus obtained has a substantially parabolic speed profile, withmaximum advancing speed substantially at the centre of the furtherportion 38 a of mixing chamber 12 and substantially zero speed at theouter pipe 32.

The gaseous mixture then enters into the portion 38 of the mixingchamber 12, where the flow of inert fluid coming from the interspacebetween outer pipe 32 and cylindrical pipe 36 is fed.

In the case in which the swirler 44 is provided, helical motion is givento the flow of inert fluid.

However, the flow of inert fluid has a speed profile that, starting fromsubstantially zero speed at the side wall 12 a, increases up to amaximum speed of the inert fluid at a determined distance from the sidewall 12 a: such a distance varies according to the operating conditionsof the speeds used and can, for example, be between 0.5 and 3 mm,preferably between 1 and 2 mm.

In the portion 38 of the mixing chamber 12, the gaseous mixture takes ona substantially parabolic speed profile, with maximum advancing speedsubstantially at the centre of the portion 38 and speed substantiallyequal to the maximum speed of the contiguous flow of inert fluid at thepredetermined distance from the side wall 12 a.

In other words, according to the invention, the gaseous mixture issurrounded, in the annular zone in contact with the side wall 12 a ofthe mixing chamber 12, by the aforementioned annular flow that advancesin the same direction as the gaseous mixture.

According to the invention, it is necessary that everywhere the maximumspeed of the inert fluid is greater than the speed of propagation of theflame, so as to preclude the possibility of the flame generated in thecombustion chamber 14 from propagating towards the mixing chamber 12. Inthe aforementioned conditions, the flame that develops in the combustionchamber 14 cannot develop in the mixing chamber 12 precisely because thegaseous mixture that can burn has a greater speed than the speed ofpropagation of the flame.

The main advantage achieved by the process for hydrocarbon partialoxidation of the present invention lies precisely in the fact ofpreventing the return of the flame into the burner with premixing. Inother words, with the present invention the very serious risk of thepossible return of the flame, which up to now has prevented the use ofburners with premixing, is overcome.

Of course, the man skilled in the art can bring numerous modificationsand variants to the process for hydrocarbon partial oxidation describedabove in order to satisfy specific and contingent requirements, all ofthese modifications and variants in any case being covered by the scopeof protection of the invention, as defined by the following claims.

1. Hydrocarbon partial oxidation process for obtaining gaseous mixturescomprising hydrogen and carbon monoxide, through a burner (10)comprising a mixing chamber (12) that has an inner side wall (12 a)extending between at least one inlet opening (23, 23 a) and an outletopening (24), independent gaseous flows of hydrocarbons and oxygen,respectively, being continuously fed into said mixing chamber (12) toform a gaseous mixture advancing towards said outlet opening (24) to befed into a combustion chamber (14) of the gaseous mixture itself,characterized in that, into said mixing chamber (12) and substantiallyin contact with the inner side wall (12 a) thereof, a flow of an inertfluid is also fed in equicurrent to said gaseous mixture, with formationof a respective annular flow of inert fluid, enveloping said gaseousmixture from which it is substantially separated by a respective innerlimit layer, said annular flow of inert fluid having, at said limitlayer, an advancing speed at least equal to the speed of propagation ofthe flame in said gaseous mixture.
 2. Partial oxidation processaccording to claim 1, characterized in that the flow of inert fluid isfed close to the outlet opening (24) of the mixing chamber (12). 3.Partial oxidation process according to claim 1, characterized in thathelical motion is given to the flow of inert fluid.
 4. Partial oxidationprocess according to claim 1, characterized in that the flow ofhydrocarbons and the flow of oxygen are fed at substantially the sameaxial speed.
 5. Partial oxidation process according to claim 4,characterized in that helical motion is given to at least one among theflow of hydrocarbons and the flow of oxygen.
 6. Partial oxidationprocess according to claim 5, characterized in that, to the flow ofhydrocarbons and to the flow of oxygen, helical motions are given inopposite directions with respect to each other.
 7. Partial oxidationprocess according to claim 6, characterized in that said oppositehelical motions have substantially the same momentum of momentum values.8. Partial oxidation process according to claim 1, characterized in thatsaid inert fluid is steam.
 9. Burner (10) for hydrocarbon partialoxidation, for obtaining gaseous mixtures comprising hydrogen and carbonmonoxide, of the type comprising a mixing chamber (12) in fluidcommunication with a combustion chamber (14), said mixing chamber (12)having an inner side wall (12 a) extending between at least one inletopening (23) and an outlet opening (24), independent gaseous flows ofhydrocarbons and oxygen, respectively, being continuously fed into saidmixing chamber (12) to form a gaseous mixture advancing towards saidoutlet opening (24) to be fed into said combustion chamber (14) of thegaseous mixture itself, characterized in that, into said mixing chamber(12) and substantially in contact with the inner side wall (12 a)thereof, a flow of inert fluid is also fed in equicurrent to saidgaseous mixture, so as to carry out the process of claim
 1. 10. Burner(10) according to claim 9, characterized in that a duct (26) carryingoxygen and a duct (28) carrying hydrocarbons arrive in said mixingchamber (12), said two ducts (26, 28) being substantially two coaxialand concentric cylindrical pipes, inner (30) and outer (32), containedin a cylindrical body (18) of the burner (10).
 11. Burner (10) accordingto claim 10, characterized in that the flow of inert fluid is fed intothe mixing chamber (12) from a duct (34) that is substantially acylindrical pipe (36), arranged coaxially and concentrically with theouter pipe (32) and contained in the cylindrical body (18).
 12. Burner(10) according to claim 11, characterized in that said cylindrical pipe(36) constitutes the inner side wall of the cylindrical body (18), anend portion of the side wall (12 a) of the mixing chamber (12) beingformed by a portion of cylindrical pipe (36) that is close to the outletopening (24) of the cylindrical body (18).
 13. Burner (10) according toclaim 12, characterized in that the outer pipe (32), coaxial to thecylindrical pipe (36), is shorter than the cylindrical pipe (36), theannular interspace between the cylindrical pipe (36) and the outer pipe(32) feeding the inert fluid.
 14. Burner (10) according to claim 13,characterized in that the inner pipe (30), coaxial to the outer pipe(32), is shorter than the outer pipe (32).
 15. Burner (10) according toclaim 14, characterized in that, in the end portion of the inner pipe(30), in the end portion of the interspace between inner pipe (30) andouter pipe (32) and in the end portion of the interspace between outerpipe (32) and cylindrical pipe (36), swirlers (40, 42, 44) are provided.16. Burner (10) according to claim 14, characterized in that, in thewall of the cylindrical pipe (36) that defines the portion ofcylindrical body (18) inserted in the combustion chamber (14), acylindrical recess (46) is provided, in fluid communication with aninlet fitting (48) and an outlet fitting (50) of a cooling fluid. 17.Burner (10) according to claim 16, characterized in that said inletfitting (48) and said outlet fitting (50) are arranged outside thecombustion chamber (14) and in that, in the cylindrical recess (46), itis provided a cylindrical baffle (52) that defines two coaxial andconcentric inner (54) and outer (56) cylindrical chambers, in fluidcommunication with each other and, respectively, with the inlet fitting(48) and with the outlet fitting (50).
 18. Burner (10) according toclaim 17, characterized in that the inner cylindrical chamber (54)defines the duct (34) carrying inert fluid and the end portion of theside wall (12 a) of the mixing chamber (12).